Spectrophotometric Determination of Cerium with Leuco Xylene Cyanol FF.

Spectrophotometric determination of cerium with leuco xylene cyanol FF.

Simultaneous determination of trace iron and aluminum by catalytic spectrophotometry based on a novel oxidation reaction of xylene cyanol FF.

A new, simple, sensitive and selective method for the simultaneous determination of trace iron and aluminum by catalytic spectrophotometry was presented, based on the catalytic effects of iron and aluminum on the discoloring reaction of xylene cyanol FF proceeded by hydrogen peroxide and potassium periodate in weak nitric acid medium. No catalytic effect was obtained in the presence of hydrogen...

Spectrophotometric determination of cerium(IV) using a phenothiazine derivative.

A simple, rapid and sensitive spectrophotometric method has been proposed for the determination of cerium(IV) using a phenothiazine derivative, propionyl promazine phosphate (PPP). This method is based on the formation of a red-colored radical cation upon a reaction of PPP with cerium(IV) in a phosphoric acid medium having maximum absorbance at 513 nm. Beer's law is valid over the concentration...

Extraction and Spectrophotometric Determination of Cerium(IV) with N-p-Chlorophenylcinnamohydroxamic Acid

N-p-Chlorophenylcinnamohydroxamic acid reacts with cerium(IV) to form an orange coloured complex, quantitatively extractable into chloroform from alkaline medium. On the basis of this sensitive colour reaction, a new method for the extraction and spectrophotometric determination of cerium(IV) has been developed. The effects of foreign ions and sever al experimental variables on the extraction a...

Spectrophotometric determination of olanzapine by its oxidation with N-bromosuccinimide and cerium(IV)sulfate.

Three simple spectrophotometric methods have been described for the assay of olanzapine in its pure and pharmaceutical formulations. The direct method (A) is based on the drug oxidation with excess of N-bromosuccinimide in acidic medium and the two indirect methods (B and C) are based on the oxidation of the drug with excess of N-bromosuccinimide and cerium(IV)sulfate, followed by the reaction ...